Part 13 Catalytic Cracking - FQE Chemicals

Part 13 Catalytic Cracking - FQE Chemicals

May 04 2016 · CATALYST REGENERATION ZONE DIVIDED INTO SECTORS IN A CATALYST REGENERATION UNIT comprising at least one zone for the combustion of coke deposited on the catalyst said combustion zone having an annular shape and being divided into at least two combustion stages each stage being divided into a number N Contacter le fournisseur

5 1 Petroleum Refining1 - US EPA

5 1 Petroleum Refining1 - US EPA

A coke removal system removes coke deposits from the walls of a high temperature passage in which hydrocarbon fuel is present The system includes a carbon-steam gasification catalyst and a water source The carbon-steam gasification catalyst is applied to the walls of the high temperature passage The water reacts with the coke deposits on the walls of the high temperature passage to remove

COKE CONTENT OF SPENT COMMERCIAL FLUID CATALYTIC …

COKE CONTENT OF SPENT COMMERCIAL FLUID CATALYTIC …

However the nature of deposited coke varies also with the nature of the catalyst 3-61 So the differ- ent behaviours of bifunctional catalysts for coke destruction can be explained either by a different activity of the catalyst for this reaction or by a different nature of coke

Burning the coke deposited on the catalyst particles

Burning the coke deposited on the catalyst particles

The establishment of the coke formation mechanisms and study of the nature of the deposited coke provide guidance for future DH catalyst optimization while reducing coke formation AB - Coke deposition is commonly identified as the main cause of deactivation for dehydrogenation DH catalysts

Insights into the coke deposited on HZSM-5 Hβ and HY

Insights into the coke deposited on HZSM-5 Hβ and HY

regenerator coke deposited on the catalyst as a result of the cracking reactions is burned off in a controlled combustion process with preheated air Regenerator temperature is usually 590 to 675°C 1100 to 1250°F The catalyst is then recycled to be mixed with fresh hydrocarbon feed

Coke deposition detection through the analysis of catalyst

Coke deposition detection through the analysis of catalyst

Oct 01 2010· The characterization of coke deposited on spent catalysts for long-chain-paraffin n-C 16 19 dehydrogenation has been investigated in this study It can be concluded that the dehydrogenation operation conditions such as TOS and temperature affect the …

Fluid catalytic cracking - Wikipedia

Fluid catalytic cracking - Wikipedia

Burning the coke deposited on the catalyst particl Question Material Balance for FCC Regenerator Problem Burning the coke deposited on the catalyst particles generates all the heat necessary for catalytic cracking Therefore the coke burning rate is a critical parameter to control the rate of cracking

Fluid Catalytic Cracking FCC FSC 432 Petroleum Refining

Fluid Catalytic Cracking FCC FSC 432 Petroleum Refining

The mechanism of coke formation on silica-alumina cracking catalysts was studied by analysis of cracking experiments with seven pure hydrocarbons at 445 C and n-hexadecane at 500 C under a variety of process conditions Coke deposits were isolated from selected catalyst samples for infrared spectral examination

US7513260B2 - In-situ continuous coke deposit removal by

US7513260B2 - In-situ continuous coke deposit removal by

Catalysts known as zeolites are vital to fuel production and other processes Coke deposits in zeolites are a costly problem in petroleum refinement and in petrochemical production PNNL and Lawrence Berkeley National Laboratory LBNL researchers zoomed in at the highest resolution yet on these problematic carbon-based deposits

Solved Exercise 6 - Material Balance For FCC Regenerator

Solved Exercise 6 - Material Balance For FCC Regenerator

Sep 18 2015· Abstract Coke deposition on catalyst will not only reduce catalytic activity and selectivity but also affect the product yield the reaction residence time the regenerator temperature and so on As a result it is necessary to measure the amount of coke deposition on catalyst This paper proposes a new method based on image analysis

Nitrogen Chemistry and Coke Transformation of FCC Coked

Nitrogen Chemistry and Coke Transformation of FCC Coked

obtain a basic understanding of catalyst decoking in the presence of steam The influence of carbon load on the porosity and pore volume of coked catalysts was also studied in order to get an information on catalyst mor-phology changes with varying coke contents Characterization of Catalytic Cracking Catalysts Regenerated by Gasifying

Pore network modeling of catalyst deactivation by coking

Pore network modeling of catalyst deactivation by coking

determine the total amount of coke the hydrogen-to-carbon ratio in the coke and the location of coke deposited on the spent catalyst Several groups have used the TPO temperature-programmed oxidation to characterize the coke on FCC catalysts 2 11 The information about the coke properties is inferred from TPO profiles

 PDF Regeneration by hydrogen treatment of bifunctional

PDF Regeneration by hydrogen treatment of bifunctional

Regeneration of the coked catalyst is an important process of fluid catalytic cracking FCC in petroleum refining however this process will emit environmentally harmful gases such as nitrogen and carbon oxides Transformation of N and C containing compounds in industrial FCC coke under thermal

Of Catalysts and Coke PNNL

Of Catalysts and Coke PNNL

Burning the coke deposited on the catalyst particles generates all the heat necessary for catalytic cracking Therefore the coke burning rate is a critical parameter to control the rate of cracking The composition of dry flue gas from the regenerator of an FCC unit is given in vol as follows

Glossary - U S Energy Information Administration EIA

Glossary - U S Energy Information Administration EIA

Jun 24 2016· Question Material Balance for FCC RegeneratorProblemBurning the coke deposited on the catalyst particles generates all the heat necessary for catalytic cracking Therefore the coke burning rate is a critical parameter to control the rate of cracking The composition of dry flue gas from the regenerator of an FCC unit is given in vol as follows Gas Volume N2 81 6CO2 15 7CO 1 5O2 …

EP0063712A2 - Immobilisation of vanadium deposited on

EP0063712A2 - Immobilisation of vanadium deposited on

Dec 12 2016· During cracking coke is formed The coke will coat the catalyst preventing it from promoting the cracking reaction The catalyst is renewed by burning off the coke deposits from the catalyst surface during regeneration The cracked hydrocarbons are separated using conventional fractionating equipment

Microwaves effectively examine the extent and type of

Microwaves effectively examine the extent and type of

reactions occur on the catalyst surface leading to the formation of carbonaceous residues usually referred to as coke or carbon which tend to physically cover the active surface Coke deposits may amount to 15 or even 20 w w of the catalyst and accordingly they may deactivate the catalyst either by covering of the active sites and by

Coke Deposited On Catalyst - lki co in

Coke Deposited On Catalyst - lki co in

A process is disclosed for the treatment of a hydrocarbon oil feed having a significant content of metals to lighter oil products by contacting the feed under conversion conditions in a conversion zone with a catalyst containing a sacial trap material sufficient to immobilize Ni-V-Na compounds Conversion conditions are such that carbonaceous material and metals are deposited on the

Characterization of coke deposited on spent catalysts for

Characterization of coke deposited on spent catalysts for

Burning the coke deposited on the catalyst particles generates all the heat necessary for catalytic cracking Therefore the coke burning rate is a critical parameter to control the rate of cracking The composition of dry flue gas from the regenerator of an FCC unit is …

Material Balance For FCC Regenerator Problem Burni

Material Balance For FCC Regenerator Problem Burni

The results are consis- coke extraction we observe that condensation of aromatic rings tent with those proposed in the literature using simpler reactants in the coke deposited on the spent catalyst increases in step with or reactor designs pore size HY H␤ HZSM-5

F SC Ex 6 - Exercise 6 Material Balance for FCC

F SC Ex 6 - Exercise 6 Material Balance for FCC

The second region is attributed to the reaction of hard coke aromatic compounds and coke deposited in the deep pores of the catalyst 28 generating CO NO and CO 2 at an elevated temperature

Coke Deposited On Catalyst - cz-eu eu

Coke Deposited On Catalyst - cz-eu eu

Sep 11 2017· Catalyst deactivation by coke deposition is a major drawback in industrial processes Here the authors show a non-intrusive microwave cavity perturbation technique as …

Burning the coke deposited on the catalyst particles

Burning the coke deposited on the catalyst particles

Coke deposited on catalytic cracking catalysts has been investigated by continuously monitoring evolved CO and CO2 during temperature-programmed oxidation TPO in a 1 O2 N2 mixture

Coke deposition and product distribution in the co

Coke deposition and product distribution in the co

Unformatted text preview Exercise 6 - Material Balance for FCC Regenerator Burning the coke deposited on the catalyst particles generates all the heat necessary for catalytic cracking Therefore the coke burning rate is a critical parameter to control the rate of cracking

Catalyst deactivation - pdfs semanticscholar org

Catalyst deactivation - pdfs semanticscholar org

Results They found zeolites s porous nature makes it a great chemical catalyst but also traps tiny clusters of carbon-containing molecules that can ultimately disrupt the catalysis process An uneven distribution of aluminum in the fresh zeolite catalyst causes an uneven distribution of coke deposits during chemical reactions

PNNL Of Catalysts and Coke

PNNL Of Catalysts and Coke

Exercise 6 - Material Balance for FCC Regenerator Problem Burning the coke deposited on the catalyst particles generates all the heat necessary for catalytic cracking Therefore the coke burning rate is a critical parameter to control the rate of cracking

Characterization of Catalytic Cracking Catalysts

Characterization of Catalytic Cracking Catalysts

Since the cracking reactions produce some carbonaceous material referred to as catalyst coke that deposits on the catalyst and very quickly reduces the catalyst reactivity the catalyst is regenerated by burning off the deposited coke with air blown into the regenerator

Temperature-Programmed Oxidation of Coke Deposited on

Temperature-Programmed Oxidation of Coke Deposited on

Coke Deposited On Catalyst Burning the coke deposited on the catalyst particles Burning the coke deposited on the catalyst particles generates all the heat necessary for catalytic cracking Therefore the coke burning rate is a critical Get Price And Support Online Burning the coke deposited on the catalyst …

coke deposited on catalyst - optimafm nl

coke deposited on catalyst - optimafm nl

Cracking reactions also deposit a significant amount of coke on the catalysts leading to the deactivation of the catalyst After removing the adsorbed hydrocarbons by steam stripping the coked catalyst is sent to the regeneration unit to burn off the coke with air

COKE FORMATION ON SILICA-ALUMINA CRACKING …

COKE FORMATION ON SILICA-ALUMINA CRACKING …

Coke deposited on catalytic cracking catalysts has been investigated by continuously monitoring evolved CO and CO2 during temperature-programmed oxidation TPO in a 1 O2 N2 mixture